TEMPO mediated oxidation of fluorinated alcohols to carboxylic acids

Fluorinated carboxylic acids (3a–f) have been prepared in good yield by oxidizing the corresponding alcohols (2a–f) in the presence of TEMPO (1) as catalyst, using oxidants like bleach and oxygen.

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Bibliographic Details
Published in:Journal of fluorine chemistry 2012-09, Vol.141, p.35-40
Main Authors: Ignatowska, Jolanta, Shyshkov, Oleg, Zipplies, Tilman, Hintzer, Klaus, Röschenthaler, Gerd-Volker
Format: Article
Language:English
Subjects:
Fluorinated alcohols
Fluorinated carboxylic acids
Oxidation
TEMPO
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Description
Summary:Fluorinated carboxylic acids (3a–f) have been prepared in good yield by oxidizing the corresponding alcohols (2a–f) in the presence of TEMPO (1) as catalyst, using oxidants like bleach and oxygen.
ISSN:0022-1139
1873-3328
DOI:10.1016/j.jfluchem.2012.06.002