Alternative synthetic routes to hydrofluoroolefins

A series of novel low boiling hydrofluoroolefins with terminal CFCH2, CHCHF and CHCF2 groups have been prepared via various synthetic routes. •Environment friendly hydrofluoroolefins with terminal CFCH2, CHCHF and CHCF2 groups have been designed and prepared.•HX or FBr elimination, Wittig-type olefi...

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Bibliographic Details
Published in:Journal of fluorine chemistry 2015-11, Vol.179, p.134-141
Main Authors: Yagupolskii, Yu. L., Pavlenko, N.V., Shelyazhenko, S.V., Filatov, A.A., Kremlev, M.M., Mushta, A.I., Gerus, I.I., Peng, Sheng, Petrov, V.A., Nappa, Mario
Format: Article
Language:English
Subjects:
Elimination
Fluorination
Olefins
Tosylates
Wittig-type olefination
β-Diketones
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Summary:A series of novel low boiling hydrofluoroolefins with terminal CFCH2, CHCHF and CHCF2 groups have been prepared via various synthetic routes. •Environment friendly hydrofluoroolefins with terminal CFCH2, CHCHF and CHCF2 groups have been designed and prepared.•HX or FBr elimination, Wittig-type olefination, fluorination with SF4.•Novel fluoroalkenes with low boiling points. A series of hydrofluoroolefins with CFCH2, CHCHF and CHCF2 groups were designed and prepared via various synthetic routes, including HX or BrF elimination, Wittig-type olefination or fluorination using SF4.
ISSN:0022-1139
1873-3328
DOI:10.1016/j.jfluchem.2015.08.001