Geochemical evolution along regional groundwater flow in a semi-arid closed basin using a multi-tracing approach

• Published in: Journal of hydrology (Amsterdam) 2024-03, Vol.632, p.130895, Article 130895
• Main Authors: Rivera Armendariz, Cristian Abraham, Banning, Andre, Cardona Benavides, Antonio
• Format: Article
• Language: English
• Subjects: Arid regions; basins; carbonates; clay; climate change; Conceptual model; Cretaceous period; evolution; geophysics; groundwater; Groundwater age; Groundwater flow; Hydrogeochemistry; irrigation; Mexico; surface water; trace elements; tritium; water quality; water supply
• ISSN: 0022-1694; 1879-2707
• DOI: 10.1016/j.jhydrol.2024.130895

[Display omitted] •Regional faults control the groundwater flow along granular and fractured aquifers.•Local, intermediate, and regional flow systems were identified in groundwater.•Groundwater geochemical evolution shows significant water–rock interaction.•Baseline water quality is important for groundwater supply planning and management. Groundwater is the main source for domestic drinking water supply, irrigation, and industrial activities in Zacatecas in central Mexico, a good example for numerous semiarid regions worldwide, however, there is insufficient information about characterization and evolution of the baseline water quality to create hydrogeological conceptual models, fundamentals for the future planning of new sources of groundwater supply for the population, especially under ongoing global climate change conditions. By a multi-method analysis that included geological, geophysical, hydrochemical and isotopic tools this investigation allowed the identification of: a) local flows, represented by shallow groundwater and shallow wells, hosted over basin fill sediments with low average temperatures (≈ 23.3 °C), variation in water types related to anthropogenic activities, low trace elements concentrations, δ18O and δ2H signatures indicating surface water and tritium being present in this system, b) intermediate flows (25 °C), identified in wells with depths of 100 to 200 m, water circulating through the basin fill sediments and the sequence of volcanic rocks characterized by intermediate concentrations of trace elements, and groundwater ages calculated for this system vary from 1,000 to 6,000 years, c) regional flows in volcanic rocks, characterized by groundwater from wells with depths of more than 200 m, high temperatures (up to 31.5 °C) and elevated concentrations of trace elements. The δ18O and δ2H signals are more homogenous and the 14C residence times for this flow system are greater than 8,000 years, and d) regional flows in Cretaceous rocks, with depths greater than 400 m, the highest temperatures (≈ 43.7 °C) and intermediate concentrations of trace elements. The δ18O and δ2H signals are homogenous and δ13C can widely be associated with carbonate shales. The hydrogeochemical evolution has been documented along a 62 km flow line to develop a robust conceptual model, reflecting the water–rock interaction in the system. Physicochemical parameters, as well as major and trace element concentrations, reflect a distinct evolution according to the