Nephelauxetic effect in high-pressure luminescence of transition-metal ion dopants

Application of the model of the nephelauxetic effect based on Harrison theory of bonding to various transition-metal dopants is reviewed. This one-parameter model describes pressure dependence of the nephelauxetic effect in various compounds with a very good accuracy. Additional studies are necessar...

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Bibliographic Details
Published in:Journal of luminescence 2007-07, Vol.125 (1), p.266-270
Main Authors: Suchocki, A., Biernacki, S.W., Grinberg, M.
Format: Article
Language:English
Subjects:
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Exact sciences and technology
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Other luminescence and radiative recombination
Physics
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Summary:Application of the model of the nephelauxetic effect based on Harrison theory of bonding to various transition-metal dopants is reviewed. This one-parameter model describes pressure dependence of the nephelauxetic effect in various compounds with a very good accuracy. Additional studies are necessary to reveal the dependence of fitting parameter on the properties of more complicated many-element compounds.
ISSN:0022-2313
1872-7883
DOI:10.1016/j.jlumin.2006.08.039