Magnetic properties and cation distribution study of nanocrystalline Ni–Zn ferrites

• Published in: Journal of magnetism and magnetic materials 2013-05, Vol.333, p.152-155
• Main Authors: Shinde, T.J., Gadkari, A.B., Vasambekar, P.N.
• Format: Article
• Language: English
• Subjects: Cation distribution; Co-precipitation technique; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Exact sciences and technology; Magnetic properties and materials; Magnetic properties of nanostructures; Magnetic property; Nanostructure; Ni–Zn ferrite; Physics
• ISSN: 0304-8853
• DOI: 10.1016/j.jmmm.2012.12.049

Nanocrystalline spinel ferrites with general formula Ni1−xZnxFe2O4 (x=0−1.0) were prepared by an oxalate co-precipitation method. Magnetic properties were investigated by means of saturation magnetization, AC susceptibility, cation distribution and Curie temperature measurements. The saturation magnetization increases with increasing concentration of zinc up to x=0.4 and then decreases with increasing zinc concentration. Investigation of the Yafet–Kittel (Y–K) angles shows the existence of Neel’s two sublattice model for x≤0.2 and Y–K model for x≥0.4 compositions. Variation of normalized AC susceptibility with temperature shows single domain particle nature for the compositions x≤0.2, whereas multi-domain particle nature for the compositions x≥0.4. Curie temperatures of the samples decrease with the increase in zinc concentration. Upadhayay’s model is used to investigate the cation distribution and hence to calculate the Curie temperature. The composition for x=1 shows paramagnetic behavior at and above room temperature. ► This method requires lower sintering temperature and smaller duration. ► Saturation magnetization was found to be improved compared to ceramic method. ► Curie temperature was found to be improved compared to ceramic method. ► Ni–Zn ferrites are used in electronic devices over a wider frequency range.