Experimental study of Cu(en)(H2O)2SO4 embedded into mesoporous silica matrix SBA-15 with the hexagonal arrangement of pores

• Published in: Journal of magnetism and magnetic materials 2023-12, Vol.588, p.171396, Article 171396
• Main Authors: Tarasenko, Róbert, Danylchenko, Petro, Zeleňák, Vladimír, Girman, Vladimír, Čižmár, Erik, Tkáč, Vladimír, Kozin, Illia, Vorobiov, Serhii, Onufriienko, Oleksandr, Orendáčová, Alžbeta, Orendáč, Martin
• Format: Article
• Language: English
• Subjects: Low-dimensional system; Magnetic dilution; mesoporous silica SBA-15
• ISSN: 0304-8853
• DOI: 10.1016/j.jmmm.2023.171396

•Encapsulation of the magnetic quasi-two-dimensional system Cu(en)(H2O)2SO4 in SBA-15.•Weakening of magnetic correlations after encapsulation.•Analysis of the EPR line shape confirmed significant magnetic dilution. In this work, we present an experimental study to find the optimal way of encapsulation of the magnetic quasi-two-dimensional system Cu(en)(H2O)2SO4 (en = ethylenediamine = C2H8N2) in mesoporous silica SBA-15 with hexagonal pore morphology with a pore size of 5 nm. Our main goal is to achieve the most significant possible degree of pore filling and to study the effect of encapsulation of complex Cu(en)(H2O)2SO4 in SBA-15 silica on the magnetic properties of the studied complex by means of electron paramagnetic resonance (EPR) and magnetization measurements. It was found that the adsorption equilibrium during the adsorption of the Cu(en)(H2O)2SO4 complex from the solution to SBA-15 was reached after only 24 h, and the samples prepared by adsorption for a longer time (72 h, 14 days) did not show an increased amount of the loaded complex. The degree of pore filling represents around 60 % of the total volume of internal pores. The analysis of temperature dependence of susceptibility, the field dependence of magnetization, and EPR spectra showed that due to the encapsulation of Cu(en)(H2O)2SO4 complex in mesoporous silica, the magnetic correlations between Cu(II) ions are significantly weakened, yielding paramagnetic behavior in the studied system.