Rotational spectrum of 2,2,2-trifluoroacetophenone

[Display omitted] •Rotational spectrum of 2,2,2-trifluoroacetophenone was measured.•The geometry of carbon skeleton was accurately determined.•Fluorination effect on geometry and electronic potential was evaluated. The rotational spectrum of 2,2,2-trifluoroacetophenone has been measured and assigned...

Full description

Saved in:
Bibliographic Details
Published in:Journal of molecular spectroscopy 2018-09, Vol.351, p.4-7
Main Authors: Lei, Juncheng, Chen, Junhua, Feng, Gang, Xia, Zhining, Gou, Qian
Format: Article
Language:English
Subjects:
2,2,2-trifluoroacetophenone
Fluorination effect
Fourier transform microwave spectroscopy
Pulsed jet
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:[Display omitted] •Rotational spectrum of 2,2,2-trifluoroacetophenone was measured.•The geometry of carbon skeleton was accurately determined.•Fluorination effect on geometry and electronic potential was evaluated. The rotational spectrum of 2,2,2-trifluoroacetophenone has been measured and assigned by supersonic-jet Fourier transform microwave spectroscopy in the 2.0–20.0 GHz region. The measurement has been also extended to all its mono-13C substituted species, from which the accurate structural parameters for the carbon skeleton have been determined.
ISSN:0022-2852
1096-083X
DOI:10.1016/j.jms.2018.06.006