Investigation of the conductivity of the lithium borosilicate glass system

• Published in: Journal of non-crystalline solids 2007-06, Vol.353 (18), p.2004-2007
• Main Authors: Kluvánek, P., Klement, R., Karáčoň, M.
• Format: Article
• Language: English
• Subjects: Borosilicates; Condensed matter: structure, mechanical and thermal properties; Conductivity; Diffusion in solids; Exact sciences and technology; Fast ion conduction; Phases and equilibria; Physics; Scanning electron microscopy; Self-diffusion and ionic conduction in nonmetals; Transport properties of condensed matter (nonelectronic)
• ISSN: 0022-3093; 1873-4812
• DOI: 10.1016/j.jnoncrysol.2007.01.064

The lithium borosilicate system (Li 2O) 0.4(B 2O) (0.6 x) (Si 2O 4) 0.6(1− x) with x = 0, 0.2, 0.3, 0.4, 0.6, and 0.8 was investigated using impedance spectroscopy. Impedance spectra were taken in the frequency range from 50 Hz to 1 MHz and in the temperature range from 100 to 280 °C. The ac- and dc-conductivity, relaxation frequency and activation energy of the dc-conductivity were extracted from the impedance spectra. The dc-conductivity of the investigated glass samples increases almost linearly from silica rich ( x = 0) to the boron rich ( x = 0.8) samples. Activation energy ( E a) was found to be 0.65 eV for high conducting sample and 0.8 eV for low conducting sample, respectively. The mixed glass-former effect was not observed on the samples studied. The effect of temperature scaling of ac-conductivity was observed, which indicates, that ionic conductivity relaxation mechanism is temperature independent for samples with x = 0, 0.2, 0.3. However, some deviations from scaling were found for the samples with higher x ( x = 0.4, 0.6, 0.8).