Green polymer electrolytes of chitosan doped with erbium triflate

Green Solid Polymer Electrolytes (SPEs) containing Er3+ ions have been prepared by solvent casting process. Chitosan was used as host polymer and the trivalent cations, as erbium triflate (Er(CF3SO3)3), have been incorporated into the matrix. The thermogravimetric analysis was used to evaluate the t...

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Bibliographic Details
Published in:Journal of non-crystalline solids 2018-02, Vol.482, p.183-191
Main Authors: Alves, R., Sentanin, F., Sabadini, R.C., Pawlicka, A., Silva, M.M.
Format: Article
Language:English
Subjects:
Chitosan
Electrochromic device
Erbium triflate
Glycerol
Science & Technology
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Summary:Green Solid Polymer Electrolytes (SPEs) containing Er3+ ions have been prepared by solvent casting process. Chitosan was used as host polymer and the trivalent cations, as erbium triflate (Er(CF3SO3)3), have been incorporated into the matrix. The thermogravimetric analysis was used to evaluate the thermal stability of the electrolytes and the minimum onset decomposition temperature was 139°C. Morphology analysis have revealed the predominant amorphous character of the analysed samples. Complex Impedance Spectroscopy was used to evaluate the conductivity of the samples as a function of temperature. The most conducting electrolyte had higher amount of glycerol (CS(ErTrif)0.05Gly0.70) and displayed 2.06×10−5 and 5.91×10−4Scm−1 at 30°C and 90°C, respectively. This SPE was chosen to assemble a small electrochromic device with glass/ITO/PB/CS(ErTrif)0.05Gly0.70/CeO2-TiO2/ITO/glass configuration, which behaviour was studied by cyclic voltammetry and transmittance.
ISSN:0022-3093
1873-4812
DOI:10.1016/j.jnoncrysol.2017.12.038