Electrochemical behaviors of PuN and (U, Pu)N in LiCl–KCl eutectic melts

• Published in: The Journal of physics and chemistry of solids 2005-02, Vol.66 (2), p.456-460
• Main Authors: Shirai, O., Kato, T., Iwai, T., Arai, Y., Yamashita, T.
• Format: Article
• Language: English
• Subjects: Chemistry; Colloidal state and disperse state; Exact sciences and technology; General and physical chemistry; Porous materials
• ISSN: 0022-3697; 1879-2553
• DOI: 10.1016/j.jpcs.2004.06.040

Electrochemical behaviors of PuN and (U, Pu)N in the LiCl–KCl eutectic melts at 773 K were investigated by cyclic voltammetry. The electrochemical dissolution of PuN and (U, Pu)N began nearly at −0.90±0.05 and −0.95±0.05 V (vs. Ag +/Ag), respectively. The rest potentials of PuN and (U, Pu)N were observed at about 0.15 V more negative potential than that of UN, in the present experimental condition. The observed rest potentials of (U, Pu)N depended on the equilibrium potential of the Pu 3+/PuN. In the cyclic voltammogram measured by use of (U, Pu)N as the working electrode, a steep rise of the positive current was observed at potentials more positive than −0.45 V in analogy with the cyclic voltammogram measured by use of UN as the working electrode. These indicate that UN and PuN in (U, Pu)N would be dissolved independently irrespective of forming the solid solution.