Sono-photocatalytic degradation of Tetracycline and Ciprofloxacin antibiotics using microwave-reflux of NiO-MoS2/rGO ternary nanocomposite

• Published in: Journal of photochemistry and photobiology. A, Chemistry. Chemistry., 2024-11, Vol.456, p.115825, Article 115825
• Main Authors: D, Divya, Paul Winston, Albin John P, Jerin, K.M., Melwin, M., Galeb, W., Ezhilarasi, S., Arulmozhi, S.
• Format: Article
• Language: English
• Subjects: Antibiotics; Ciprofloxacin; Microwave assisted refluxing method; NiO-MoS2/rGO nanocomposite; Sono-photocatalytic degradation; Tetracycline
• ISSN: 1010-6030; 1873-2666
• DOI: 10.1016/j.jphotochem.2024.115825

•NiO/MoS2/rGO ternary nanocomposites were synthesized via microwave-assisted reflux method.•NiMG-50 is studied towards sonocatalytic, photocatalytic and sono-photocatalytic degradation.•NiMG-50 composite exhibited superior sono-photocatalaytic degradation of TTC and CIP.•̇OH and ̇O2– radicals are the primary active agents participating in the degradation of the antibiotics.•The NiMG-50 has a Z-scheme charge transfer and migration mechanism. In this study, NiO-MoS2/rGO nanocomposites were synthesized successfully by a simple microwave assisted refluxing method by varying the mass ratios of rGO. The NiMG-50 ternary nanocomposite has been applied by sonocatalytic, photocatalytic and sono-photocatalytic degradation for the removal of tetracycline (TTC) and ciprofloxacin (CIP) antibiotics. Physicochemical properties of the synthesized samples were characterized by Powder X-ray Diffraction (PXRD), Energy Dispersive X-ray Spectroscopy (EDAX) and X-ray Photoelectron Spectroscopy (XPS) corroborated the phase purity of NiMG-50 nanocomposite. The High Resolution Scanning Electron Microscopy (HR-SEM) image reveals the zigzag arrangements of NiO nanoflakes over MoS2 and rGO sheets. The tight contact of platelet shaped-NiO NP’s and curled layer-MoS2 on the sheets of rGO results in the separation of photo-induced e--h+ pairs as demonstrated by the High Resolution Transmission Electron Microscopy (HR-TEM) analysis. Optical properties reveal a reduced band gap and enhanced separation efficiency with fast charge transfer rate, improving the organic pollutant degradation efficiency. NiMG-50 demonstrated a good catalytic activity against TTC and CIP in sono-photocatalytic process with an efficiency of 94.10 % and 83.96 % at 35 and 90 min, respectively. Simultaneously, the experimental results showed that the NiMG-50 composite follows the pseudo-first order reaction kinetics with a rate constant (KSP) value of 0.077 min−1 and 0.015 min−1 for TTC and CIP. The radical trapping test and degradation mechanism indicated that the continuous contribution of ̇OH and ̇O2– reactive radicals are the major ones responsible for the active involvement in the degradation reaction. This research work gives a fresh prospects to the as prepared NiMG catalyst as an efficient composite with a good applicability for the sono-photocatalytic degradation of pharmaceutical products.