The effect of adsorption of thiourea on the particle size of supported platinum nanocatalysts synthesized by chemical reduction

• Published in: Journal of power sources 2008-01, Vol.175 (1), p.18-25
• Main Authors: Ciapina, E.G., Carbonio, E.A., Colmati, F., Gonzalez, E.R.
• Format: Article
• Language: English
• Subjects: Applied sciences; Crystal growth; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fuel cells; Particle size; Pt/C catalyst; Thiourea adsorption
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2007.09.094

In this work, carbon-supported platinum nanoparticles were synthesized in the presence of varying concentrations of thiourea (TU). Because of the presence of the sulfur atom, thiourea adsorbs strongly on the forming Pt nuclei during the synthesis, affecting the rate and the extent of growth. High-intensity X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM) were used to probe the effect on the crystallite size and particle size, respectively, revealing a decrease in both mean crystallite and the mean particle size for increasing concentrations of thiourea during the synthesis. An adsorption isotherm for the adsorption of thiourea on platinum nanoparticles is also discussed. Cyclic voltammetry was used to check the effect of TU on the particles as well as to obtain further knowledge on both adsorption and electrochemical oxidation behavior of thiourea on Pt surfaces. Thermal treatment effectively cleaned the electrode surface, thus providing an easy way to remove adsorbed species from the Pt surface.