Effect of the deposition temperature on the electrochemical properties of La0.6Sr0.4Co0.8Fe0.2O3−δ cathode prepared by conventional spray-pyrolysis

• Published in: Journal of power sources 2014-06, Vol.255, p.308-317
• Main Authors: Marrero-López, D., Romero, R., Martín, F., Ramos-Barrado, J.R.
• Format: Article
• Language: English
• Subjects: Applied sciences; Direct energy conversion and energy accumulation; Electrical engineering. Electrical power engineering; Electrical power engineering; Electrochemical conversion: primary and secondary batteries, fuel cells; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fuel cell; Fuel cells; Impedance spectroscopy; La0.6Sr0.4Co0.8Fe0.2O3−δ; Microstructure; Spray-pyrolysis
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2014.01.021

La0.6Sr0.4Co0.8Fe0.2O3−δ (LSCF) cathodes have been deposited by conventional spray pyrolysis on Ce0.8Gd0.2O1.9 (CGO) electrolytes at different temperatures between 250 and 450 °C, obtaining electrodes with different microstructure and porosity. Highly porous and macroporous electrodes are obtained at deposition temperatures of 250 °C and 450 °C, respectively, with an average grain size of 30–50 nm. The influence of the post-annealing treatment on the microstructure and on the electrochemical properties is investigated by scanning electron microscopy and impedance spectroscopy in air and as a function of the oxygen partial pressure to identify the different contributions to the polarization. Samples annealed at 650 °C show similar values of area specific resistance 0.04–0.06 Ω cm2 at a measured temperature of 650 °C. However, after annealing the samples at 850 °C, the ASR values increase up to 0.1–0.6 Ω cm2 with the lowest value corresponding to the film deposited at 250 °C due to the large porosity and surface area of this film. The performance degradation upon annealing is attributed to decreasing reaction sites induced by grain growth and densification. [Display omitted] •LSCF film cathodes prepared by conventional spray pyrolysis on CGO electrolytes.•Porous, cracked and macroporous electrodes were obtained between 250 and 450 °C.•All cells annealed at 650 °C showed ASR values as low as 0.04 Ω cm2 at 650 °C.•Porous electrodes exhibited lower performance degradation with the thermal treatment.