Oxygen ion conduction in barium doped LaInO3 perovskite oxides

• Published in: Journal of power sources 2014-12, Vol.267, p.723-730
• Main Authors: Kim, Hye-Lim, Kim, Shin, Lee, Kyu-Hyung, Lee, Hong-Lim, Lee, Ki-Tae
• Format: Article
• Language: English
• Subjects: Activation energy; Conductivity; Oxygen ion conduction; Perovskite oxide; Tolerance factor
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2014.06.006

Oxygen ion conduction behaviors of the 0–5 mol% excess Ba-doped La0.6Ba0.4InO3−δ cubic perovskite oxides have been investigated to elucidate their potential as electrolyte materials. The highest conductivity, 5.6 × 10−2 S cm−1 at 800 °C, is obtained at the 3 mol% excess Ba-doped composition benefiting from a supplementation of Ba2+ ions on the vacant A-site generated by the volatilization during the heat-treatment processes. Interestingly, all the samples except the undoped composition show curved electrical conductivity behavior in the Arrhenius plot. The activation energy is 0.50–0.52 eV in the high-temperature region above 900 °C, which is slightly lower than that of the doped LaGaO3 system. Moreover, all the samples show significantly lower activation energy values of both the high- and low-temperature regions compared with yttria-stabilized zirconia. The 3 mol% excess Ba-doped La1−xBaxInO3−δ (0.4 ≤ x ≤ 0.8) sample has also been studied. All of the compositions show a cubic perovskite structure and a nearly pure oxygen ion conduction behavior in a dry atmosphere even when p(O2) = 1atm. The composition of x = 0.4 exhibits the highest oxygen ion conductivities. •3 mol% excess Ba-doped La1−xBaxInO3−δ (0.4 ≤ x ≤ 0.8) is a cubic perovskite structure.•La1−xBaxInO3−δ (0.4 ≤ x ≤ 0.8) is nearly pure oxygen ion conductor in a dry atmosphere.•La0.6Ba0.4InO3−δ exhibited the highest conductivity of 5.6 × 10−2 S cm−1 at 800 °C.•Activation energy was slightly lower than that of the doped LaGaO3 system.