Graphene quantum dot antennas for high efficiency Förster resonance energy transfer based dye-sensitized solar cells

• Published in: Journal of power sources 2017-03, Vol.343, p.39-46
• Main Authors: Subramanian, Alagesan, Pan, Zhenghui, Rong, Genlan, Li, Hongfei, Zhou, Lisha, Li, Wanfei, Qiu, Yongcai, Xu, Yijun, Hou, Yuan, Zheng, Zhaozhao, Zhang, Yuegang
• Format: Article
• Language: English
• Subjects: Dye-sensitized solar cell; Förster resonance energy transfer; Graphene quantum dot antenna; Synergistic interaction
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2017.01.043

The light harvesting efficiency of an acceptor dye can be enhanced by judicious choice and/or design of donor materials in the Förster resonance energy transfer (FRET) based dye-sensitized solar cells (DSSCs). In this work, we explore graphene quantum dots (GQDs) as energy relay antennas for the high power conversion efficiency Ru-based N719 acceptor dyes. The absorption, emission, and time decay spectral results evidence the existence of the FRET, the radiative energy transfer (RET), and a synergistic interaction between GQDs and N719 dye. The FRET efficiency is measured to be 27%. The GQDs co-sensitized DSSC achieves an efficiency (ƞ) of 7.96% with a Jsc of 16.54 mAcm−2, which is 30% higher than that of a N719-based DSSC. GQDs also reduce the charge recombination, which results in an increased open-circuit voltage up to 770 mV. The incident photon-to-current conversion efficiency and UV–Vis absorption measurement reveal that the enhanced absorption of the GQDs antennas is responsible for the improved Jsc in the whole UV–Visible region, while the RET/FRET and the synergistic effect contribute to the significant increase of Jsc in the UV region. •Graphene quantum dot acts as good energy donors for acceptor N719 dye.•Graphene quantum dot exhibits a weak molecular interaction with N719 dye.•Light absorption of N719 is increased via Förster resonance energy transfer.•The enhanced light absorption improves photocurrent density by 30%.•Cosensitization of graphene quantum dot improves charge collection efficiency.