A high-voltage honeycomb-layered Na4NiTeO6 as cathode material for Na-ion batteries

We report a high-voltage Na4NiTeO6 cathode material for Na-ion batteries. It delivers 111 mAh g−1 at 0.1 C with 87% contribution from the inductive effect at the voltage beyond 3.5 V. With addition of fluoroethylene carbonate, stable fluorine-containing solid electrode interface is formed, which sig...

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Bibliographic Details
Published in:Journal of power sources 2017-08, Vol.360, p.319-323
Main Authors: Yang, Ze, Jiang, Yan, Deng, Liangzi, Wang, Ting, Chen, Shuo, Huang, Yunhui
Format: Article
Language:English
Subjects:
Cathode material
High-voltage
Na-ion batteries
Na4NiTeO6
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Summary:We report a high-voltage Na4NiTeO6 cathode material for Na-ion batteries. It delivers 111 mAh g−1 at 0.1 C with 87% contribution from the inductive effect at the voltage beyond 3.5 V. With addition of fluoroethylene carbonate, stable fluorine-containing solid electrode interface is formed, which significantly improve its cyclic performance. Our results provide insights into designing sodium layered cathode materials with high voltage, which will benefit for the development of high energy Na-ion batteries. •Honeycomb-layered structured Na4NiTeO6 is reported for the first time.•Na4NiTeO6 is evaluated as cathode material for Na-ion batteries.•87% capacity is contributed from the inductive effect at the voltage beyond 3.5 V.
ISSN:0378-7753
1873-2755
DOI:10.1016/j.jpowsour.2017.06.014