Enhancing the capacity of activated carbon electrodes by a redox mediator pair for the fabrication of flexible asymmetric solid-state supercapacitors

• Published in: Journal of power sources 2019-04, Vol.418, p.24-32
• Main Authors: Fang, Jianhui, Miao, Xiaofei, Zhang, Xiangxin, Liu, Yongchuan, Chen, Sujing, Chen, Yuanqiang, Wang, Wei, Zhang, Yining
• Format: Article
• Language: English
• Subjects: Activated carbon electrode; Asymmetric supercapacitor; Flexible supercapacitor; Redox mediator; Solid-state supercapacitor
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2019.01.076

We use a redox mediator pair - hydroquinone (for positive electrode) and sodium anthraquinone-2-sulfonate (for negative electrode) - to treat the activated carbon electrodes for fabricating asymmetric supercapacitors. This simple adsorption-based treatment improves the specific capacity of the activated carbon electrode from 69.3 mAh g−1 to 300.4 mAh g−1 (negative electrode) and 63.5 mAh g−1 to 301.1 mAh g−1 (positive electrode). The charge balance between the two electrodes is achieved by synchronous potential measurements on redox reaction of hydroquinone and anthraquinone-2-sulfonate. Under 5 A g−1, the asymmetric supercapacitor delivers a high energy density of 37.1 Wh kg−1 with the power density of 2087 W kg−1. Meanwhile, the asymmetric supercapacitor demonstrates excellent cycling stability, capable of retaining 81.8% of its capacity after 20000 cycles at 10 A g−1. A flexible solid-state asymmetric supercapacitor is fabricated with the treated electrode-pair and exhibits excellent flexing stability, high volumetric energy density (2.20 mWh cm−3 at 0.017 W cm−3), and good cycling stability (>91% capacity retention after 3000 cycles), which holds great potential for application in wearable electronics. [Display omitted] •Hydroquinone and Anthraquinone-2-sulfonate are used for capacity enhancement.•Electrode charge balance is achieved via synchronous potential measurements.•At 5 A g−1, the supercapacitor shows high energy density of 37.1 Wh kg−1.•The supercapacitor exhibits maximum power density of 2087 W kg−1.•The solid-state device exhibits high volumetric energy density of 2.20 mWh cm−3.