Unraveling the cohesive and interfacial adhesive strengths of electrodes for automotive fuel cells

• Published in: Journal of power sources 2020-04, Vol.455, p.227928, Article 227928
• Main Authors: Byun, Seoungwoo, Yu, Jung-Han, Choi, Jaecheol, Yun, Sukhwan, Roh, Youngjoon, Dzakpasu, Cyril Bubu, Park, Sun Ho, Oh, Jong-Gil, Hong, Bo Ki, Lee, Yong Min
• Format: Article
• Language: English
• Subjects: Cohesive and adhesive strengths; Ionomer binders; Membrane electrode assemblies; Polymer electrolyte membrane fuel cells; SAICAS
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2020.227928

Despite the pressing need to develop highly durable electrodes for electric vehicles powered by polymer electrolyte membrane fuel cells (PEMFCs), evaluating the mechanical robustness of the electrodes in membrane electrode assemblies (MEAs) has proven challenging because the electrodes are intrinsically porous and brittle. Herein, we propose a novel technique for effectively quantifying the mechanical robustness of the electrodes using a surface and interfacial cutting analysis system (SAICAS). The SAICAS enables the separate quantification of cohesion and adhesion of PEMFC electrodes. We find that the adhesion at the interface is higher than the cohesion in the bulk owing to a larger intermolecular diffusion at the interface than in the bulk. Also, the SAICAS could reliably quantify the cohesion and adhesion of PEMFC electrodes having different ionomer contents and assembly temperatures. Our findings are intriguing and will be useful for the efficient and effective design and development of robust electrodes and MEAs. •Cohesive/adhesive strength of the electrode is quantified by using SAICAS method.•Component and composition within the electrode layer of MEAs are confirmed.•Relation between assembly temperature and interfacial adhesion is analyzed.•Intermolecular diffusion by ionomer content can be analyzed using SAICAS method.