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High stable rate cycling performances of microporous carbon spheres/selenium composite (MPCS/Se) cathode as lithium–selenium battery
Loading selenium (Se) into microporous carbon spheres (MPCS) for the use as a cathode material is an efficient method for reducing the volume expansion and dissolution of polyselenides in the lithium-selenium (Li–Se) batteries during cycling. In this study, we produced MPCSs from glucose using a sim...
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Published in: | Journal of power sources 2020-10, Vol.473, p.228611, Article 228611 |
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description | Loading selenium (Se) into microporous carbon spheres (MPCS) for the use as a cathode material is an efficient method for reducing the volume expansion and dissolution of polyselenides in the lithium-selenium (Li–Se) batteries during cycling. In this study, we produced MPCSs from glucose using a simple and efficient hydrothermal synthesis method, followed by activation of the MPCS with KOH. Selenium particles were homodispersed in the micropores of MPCS by a typical melt-diffusion process. The obtained MPCS/Se composites used as a cathode of Li–Se batteries show high Se loading of nearly 45%, and high capacities as well as stable cycling performance in both carbonate-based LiPF6 electrolyte (565 mAh g−1 at 1 C after 500 cycles) and ether-based LiTFSI electrolyte (480 mAh g−1 at 1 C after 500 cycles). Notably, an outstanding rate capability in the carbonate-based electrolyte and a coulombic efficiency of nearly 100% in both types of electrolytes were observed. The microporous structure of the MPCS material with high conductivity contributes to the excellent electrochemical properties and rate capability, effectively alleviating volume expansion and suppressing dissolution of polyselenides.
[Display omitted]
•Selenium was encapsulated into microporous carbon spheres for Li–Se batteries.•The discharge behaviors of Li–Se batteries in different electrolytes were investigated.•The MPCS/Se composite showed outstanding rate capability and cycling stability. |
doi_str_mv | 10.1016/j.jpowsour.2020.228611 |
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[Display omitted]
•Selenium was encapsulated into microporous carbon spheres for Li–Se batteries.•The discharge behaviors of Li–Se batteries in different electrolytes were investigated.•The MPCS/Se composite showed outstanding rate capability and cycling stability.</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/j.jpowsour.2020.228611</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Electrolyte ; Lithium-selenium battery ; Microporous carbon spheres</subject><ispartof>Journal of power sources, 2020-10, Vol.473, p.228611, Article 228611</ispartof><rights>2020 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c312t-59256174545fc8a62025413a5394e0bae83ee198c2615a5e3066ab24f76f5c403</citedby><cites>FETCH-LOGICAL-c312t-59256174545fc8a62025413a5394e0bae83ee198c2615a5e3066ab24f76f5c403</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Lei, Zhenyu</creatorcontrib><creatorcontrib>Lei, Youyi</creatorcontrib><creatorcontrib>Liang, Xinmiao</creatorcontrib><creatorcontrib>Yang, Li</creatorcontrib><creatorcontrib>Feng, Jiwen</creatorcontrib><title>High stable rate cycling performances of microporous carbon spheres/selenium composite (MPCS/Se) cathode as lithium–selenium battery</title><title>Journal of power sources</title><description>Loading selenium (Se) into microporous carbon spheres (MPCS) for the use as a cathode material is an efficient method for reducing the volume expansion and dissolution of polyselenides in the lithium-selenium (Li–Se) batteries during cycling. In this study, we produced MPCSs from glucose using a simple and efficient hydrothermal synthesis method, followed by activation of the MPCS with KOH. Selenium particles were homodispersed in the micropores of MPCS by a typical melt-diffusion process. The obtained MPCS/Se composites used as a cathode of Li–Se batteries show high Se loading of nearly 45%, and high capacities as well as stable cycling performance in both carbonate-based LiPF6 electrolyte (565 mAh g−1 at 1 C after 500 cycles) and ether-based LiTFSI electrolyte (480 mAh g−1 at 1 C after 500 cycles). Notably, an outstanding rate capability in the carbonate-based electrolyte and a coulombic efficiency of nearly 100% in both types of electrolytes were observed. The microporous structure of the MPCS material with high conductivity contributes to the excellent electrochemical properties and rate capability, effectively alleviating volume expansion and suppressing dissolution of polyselenides.
[Display omitted]
•Selenium was encapsulated into microporous carbon spheres for Li–Se batteries.•The discharge behaviors of Li–Se batteries in different electrolytes were investigated.•The MPCS/Se composite showed outstanding rate capability and cycling stability.</description><subject>Electrolyte</subject><subject>Lithium-selenium battery</subject><subject>Microporous carbon spheres</subject><issn>0378-7753</issn><issn>1873-2755</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkL1OwzAUhS0EEqXwCsgjDEn9EzvpBqqAIhWBVJgtx71pHCVxZKegbky8AG_Ik5CqwMp0l3M-3fMhdE5JTAmVkyquOvcW3MbHjDASM5ZJSg_QiGYpj1gqxCEaEZ5mUZoKfoxOQqgIIZSmZIQ-5nZd4tDrvAbsdQ_YbE1t2zXuwBfON7o1ELArcGONd53zbhOw0T53LQ5dCR7CJEANrd002Limc8EOlIuHp9lysoTLIduXbgVYB1zbvhxiX--ff41c9z347Sk6KnQd4OznjtHL7c3zbB4tHu_uZ9eLyHDK-khMmZA0TUQiCpNpOewVCeVa8GkCJNeQcQA6zQyTVGgBnEipc5YUqSyESQgfI7nnDltC8FCozttG-62iRO1sqkr92lQ7m2pvcyhe7YswfPdqwatgLAxuVtaD6dXK2f8Q35k4hQI</recordid><startdate>20201015</startdate><enddate>20201015</enddate><creator>Lei, Zhenyu</creator><creator>Lei, Youyi</creator><creator>Liang, Xinmiao</creator><creator>Yang, Li</creator><creator>Feng, Jiwen</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20201015</creationdate><title>High stable rate cycling performances of microporous carbon spheres/selenium composite (MPCS/Se) cathode as lithium–selenium battery</title><author>Lei, Zhenyu ; Lei, Youyi ; Liang, Xinmiao ; Yang, Li ; Feng, Jiwen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c312t-59256174545fc8a62025413a5394e0bae83ee198c2615a5e3066ab24f76f5c403</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Electrolyte</topic><topic>Lithium-selenium battery</topic><topic>Microporous carbon spheres</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lei, Zhenyu</creatorcontrib><creatorcontrib>Lei, Youyi</creatorcontrib><creatorcontrib>Liang, Xinmiao</creatorcontrib><creatorcontrib>Yang, Li</creatorcontrib><creatorcontrib>Feng, Jiwen</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of power sources</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lei, Zhenyu</au><au>Lei, Youyi</au><au>Liang, Xinmiao</au><au>Yang, Li</au><au>Feng, Jiwen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High stable rate cycling performances of microporous carbon spheres/selenium composite (MPCS/Se) cathode as lithium–selenium battery</atitle><jtitle>Journal of power sources</jtitle><date>2020-10-15</date><risdate>2020</risdate><volume>473</volume><spage>228611</spage><pages>228611-</pages><artnum>228611</artnum><issn>0378-7753</issn><eissn>1873-2755</eissn><abstract>Loading selenium (Se) into microporous carbon spheres (MPCS) for the use as a cathode material is an efficient method for reducing the volume expansion and dissolution of polyselenides in the lithium-selenium (Li–Se) batteries during cycling. In this study, we produced MPCSs from glucose using a simple and efficient hydrothermal synthesis method, followed by activation of the MPCS with KOH. Selenium particles were homodispersed in the micropores of MPCS by a typical melt-diffusion process. The obtained MPCS/Se composites used as a cathode of Li–Se batteries show high Se loading of nearly 45%, and high capacities as well as stable cycling performance in both carbonate-based LiPF6 electrolyte (565 mAh g−1 at 1 C after 500 cycles) and ether-based LiTFSI electrolyte (480 mAh g−1 at 1 C after 500 cycles). Notably, an outstanding rate capability in the carbonate-based electrolyte and a coulombic efficiency of nearly 100% in both types of electrolytes were observed. The microporous structure of the MPCS material with high conductivity contributes to the excellent electrochemical properties and rate capability, effectively alleviating volume expansion and suppressing dissolution of polyselenides.
[Display omitted]
•Selenium was encapsulated into microporous carbon spheres for Li–Se batteries.•The discharge behaviors of Li–Se batteries in different electrolytes were investigated.•The MPCS/Se composite showed outstanding rate capability and cycling stability.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.jpowsour.2020.228611</doi></addata></record> |
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subjects | Electrolyte Lithium-selenium battery Microporous carbon spheres |
title | High stable rate cycling performances of microporous carbon spheres/selenium composite (MPCS/Se) cathode as lithium–selenium battery |
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