Ionic liquid electrolytes for high-voltage, lithium-ion batteries

• Published in: Journal of power sources 2020-12, Vol.479, p.228791, Article 228791
• Main Authors: Brutti, S., Simonetti, E., De Francesco, M., Sarra, A., Paolone, A., Palumbo, O., Fantini, S., Lin, R., Falgayrat, A., Choi, H., Kuenzel, M., Passerini, S., Appetecchi, G.B.
• Format: Article
• Language: English
• Subjects: bis(fluorosulfonyl)imide; bis(trifluoromethylsulfonyl)imide; Ethyl-methyl-imidazolium; Ionic liquids; Lithium-rich nickel-manganese oxide cathodes; Tetra-alkyl-ammonium
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2020.228791

Ionic liquid electrolytes based on imidazolium and tetra-alkyl-ammonium cations, coupled with bis(perfluroalkylsulfonyl)imide anions, are specifically tailored for lithium battery systems operating up to almost 5 V. Their ion transport properties and the electrochemical stability are herein reported and compared. Specifically, the effect of temperature and lithium salt incorporation as well as the nature of the main cation side group are discussed. Preliminary battery cycling tests of the selected ionic liquid electrolytes employing high-voltage, lithium-rich layered oxide positive electrodes, (i.e., Li1·2Ni0·2Mn0·6O2) are also reported. Also, potential anodic dissolution phenomena of the aluminum current collector, due to the presence of the ionic liquid electrolytes, were preliminarily investigated. •Ionic liquid electrolyte families for lithium-ion batteries were designed.•Eco-friend synthesis route.•Fast ion transport properties (>10−3 S cm−1) even at low temperatures (−10 °C).•High anodic stability (4.8 V) recorded towards carbon working electrodes.•Reversible capacity approaching 200 mA h g−1 in Li/LRMN cells.