Synthesis and optical properties of novel Gd3+-doped BaZn2(PO4)2 glass-ceramics for radiation detection applications

• Published in: Journal of rare earths 2022-12, Vol.40 (12), p.1927-1934
• Main Authors: Li, Wanli, Chen, Zhaoyang, Xu, Jie, Zhao, Pengjun, Fan, Yanwei, He, Chengfa
• Format: Article
• Language: English
• Subjects: Continuous wave-optically stimulated luminescence; Glass-ceramics; Photoluminescence; Radiation dosimetry; Rare earths; Thermoluminescence
• ISSN: 1002-0721; 2509-4963
• DOI: 10.1016/j.jre.2021.11.010

45P2O5-15BaO-25ZnO-15B2O3 glasses doped with different concentrations (0, 0.1, 0.25, 0.5, and 0.75 mol%) of Gd3+ were prepared by a melt-quenching method and treated to fabricate glass-ceramics containing BaZn2(PO4)2 crystals by controllable crystallization. The structural, optical, and dosimetric properties were investigated. FTIR spectra indicates the glasses were composed of [PO4], [BO3], and [BO4] basic structural units. The XRD pattern analysis indicated the samples contained BaZn2(PO4)2 crystals. In the photoluminescence (PL) spectra, two emission bands were observed at 307 and 313 nm due to the 6P5/2→8S7/2 and 6P7/2→8S7/2 transitions of Gd3+, respectively. The OSL dosimetric properties of glass-ceramics were studied further under beta radiation of 90Sr. The optimal Gd3+ doping concentration of 0.5 mol% was determined. The fading of the OSL signal shows that the CW-OSL signal of Gd3+-doped BaZn2(PO4)2 glass-ceramics decays by about 58.95% within 120 h, and the intensity remains stable thereafter. The thermoluminescence (TL) curve has three peaks at 164, 240, and 344 °C. Minimum detectable dose (MDD) of the 0.5 mol% Gd3+-doped BaZn2(PO4)2 glass-ceramics was calculated as 0.675 mGy. The samples also exhibit good signal reusability and a broad linear dose-response range (0.3–500 Gy). Results show the excellent dosimetric properties of Gd3+-doped BaZn2(PO4)2 glass-ceramics and their potential application in radiation dosimetry. The excitation spectra of Gd3+-doped BaZn2(PO4)2 glass–ceramics show three excitation bands around 247 nm (8S7/2→6D7/2), 254 nm (8S7/2→6D9/2) and 276 nm (8S7/2→6I13/2). The emission spectra of the samples show two emission bands at 307 and 313 nm due to the 6P5/2→8S7/2 and 6P7/2→8S7/2 transitions of Gd3+, respectively. The dose response is well linear in the range of 0.3–500 Gy with R2 equal to 0.9983. [Display omitted]