Boron-bearing species in ceramic matrix composites for long-term aerospace applications

• Published in: Journal of solid state chemistry 2004-02, Vol.177 (2), p.449-456
• Main Authors: Naslain, R, Guette, A, Rebillat, F, Pailler, R, Langlais, F, Bourrat, X
• Format: Article
• Language: English
• Subjects: B 2O 3-healing phase; B 4C/SiC multilayered matrices; C(B) and BN interphases; Ceramic matrix composites (CMC); CVD-processing
• ISSN: 0022-4596; 1095-726X
• DOI: 10.1016/j.jssc.2003.03.005

Boron-bearing refractory species are introduced in non-oxide ceramic matrix fibrous composites (such as SiC/SiC composites) to improve their oxidation resistance under load at high temperatures with a view to applications in the aerospace field. B-doped pyrocarbon and hex-BN have been successfully used as interphase (instead of pure pyrocarbon) either as homogeneous or multilayered fiber coatings, to arrest and deflect matrix cracks formed under load (mechanical fuse function) and to give toughness to the materials. A self-healing multilayered matrix is designed and used in a model composite, which combines B-doped pyrocarbon mechanical fuse layers and B- and Si-bearing compound (namely B 4C and SiC) layers forming B 2O 3-based fluid healing phases when exposed to an oxidizing atmosphere. All the materials are deposited by chemical vapor infiltration. Lifetimes under tensile loading of several hundreds hours at high temperatures are reported.