Photoelectrical, photophysical and photocatalytic properties of Al based MOFs: MIL-53(Al) and MIL-53-NH2(Al)

• Published in: Journal of solid state chemistry 2016-01, Vol.233, p.194-198
• Main Authors: An, Yang, Li, Huiliang, Liu, Yuanyuan, Huang, Baibiao, Sun, Qilong, Dai, Ying, Qin, Xiaoyan, Zhang, Xiaoyang
• Format: Article
• Language: English
• Subjects: Alumimum; Electron tunneling; MOFs; Photocatalysis
• ISSN: 0022-4596; 1095-726X
• DOI: 10.1016/j.jssc.2015.10.037

Two Al based MOFs (MIL-53(Al) and MIL-53-NH2 (Al)) were synthesized, and their photoelectrical, photophysical and photocatalytic properties towards oxygen evolution from water were investigated. Different from the ligand to metal charge transfer process previously reported, we proposes a new photocatalytic mechanism based on electron tunneling according to the results of theoretical calculation, steady state and time resolved fluorescence spectra. The organic linkers absorb photons, giving rise to electrons and holes. Then, the photogenerated electrons tunnel through the AlO6-octahedra, which not only inhibit the recombination of photogenerated charge carriers, but also is a key factor to the photocatalytic activity of Al based MOFs. The photoelectrical, photophysical and photocatalytic properties towards oxygen evolution from water of two Al based MOFs were investigated. A new photocatalytic mechanism was proposed based on electron tunneling according to the results of both theoretical calculation and steady state, time resolved fluorescence spectra. The electron tunneling process not only inhibit the recombination of photogenerated charge carriers, but also is a key factor to the photocatalytic activity of Al based MOFs. [Display omitted]