Preparation of black hollow TiO2 nanotube-coated PDA@Ag2S heterostructures for efficient photocatalytic reduction of Cr(VI)

• Published in: Journal of solid state chemistry 2022-03, Vol.307, p.122865, Article 122865
• Main Authors: Jiang, Jun, Chen, Zhidong, Wang, Peng, Gu, Pei-Yang, Liu, Jiadi, Zhang, Zhuzhu, Xu, Qingfeng
• Format: Article
• Language: English
• ISSN: 0022-4596; 1095-726X
• DOI: 10.1016/j.jssc.2021.122865

At present, hexavalent chromium (Cr(VI)) has a serious impact on the water environment and human beings since it can be easily absorbed by the human body, lethal to aquatic organisms and carcinogenic to humans. Based on this, a black hollow TiO2 nanotube supported polydopamine (PDA)@Ag2S composite photocatalytic material was prepared, which can be used for the efficient photocatalytic reduction of Cr(VI) in wastewater. Both black hollow TiO2 and Ag2S have the shortcoming of undergoing ready recombination of photogenerated carriers. The introduction of PDA can not only improve the photogeneration of composite photocatalytic materials, but also broaden the absorption range in the visible-light region. A detailed mechanism for the TiO2-x@PDA@Ag2S photocatalytic system has been proposed at the same time. This work provides a new methodology for the design and synthesis of sandwich organic-inorganic hybrid photocatalytic materials. Hexavalent chromium (Cr(VI)) has a serious impact on the water environment and human beings. Herein, a series of TiO2-x@PDA@Ag2S organic-inorganic hybrid photocatalysts containing a core-shell structure were successfully prepared for the efficient photocatalytic reduction of Cr(VI) under the visible light irradiation in wastewater. [Display omitted] •A series of TiO2-x@PDA@Ag2S organic-inorganic hybrid photocatalysts containing a core-shell structure were prepared.•TiO2-x@PDA@Ag2S displayed good Cr(VI) photoreduction activities.•TiO2-x@PDA@Ag2S showed high photocatalytic activity compared with TiO2-x@PDA and PDA@Ag2S.