Rapid cationic dye adsorption on polyphenol-extracted coffee grounds—A response surface methodology approach

• Published in: Journal of the Taiwan Institute of Chemical Engineers 2014-07, Vol.45 (4), p.1691-1699
• Main Authors: Pavlović, Marija D., Buntić, Aneta V., Mihajlovski, Katarina R., Šiler-Marinković, Slavica S., Antonović, Dušan G., Radovanović, Željko, Dimitrijević-Branković, Suzana I.
• Format: Article
• Language: English
• Subjects: Adsorption; Coffee ground; Crystal Violet dye; Response surface methodology (RSM)
• ISSN: 1876-1070; 1876-1089
• DOI: 10.1016/j.jtice.2013.12.018

•Coffee ground is promising biosorbent with economical advantages in waste water treatments.•Coffee ground provides fast and efficient adsorption process of cationic dyes.•The Box–Behnken design is suitable for optimization of dye adsorption process on coffee ground. The Box–Behnken design under the response surface methodology (RSM) with five interacting parameters (adsorbent dose, initial dye concentration, time of agitation, initial solution pH and time of the adsorbent microwave activation) was employed to interpret the adsorption characteristics of cationic dye onto polyphenol-extracted coffee grounds in water solutions. Experimental results indicated that coffee ground is excellent low-cost biosorbent with dye removal ability more than 95% for a very short time (under conditions of 250mg/L initial dye concentration and 15g/L of adsorbent dose). The maximum adsorption capacity was 36.82mg/g, whereby the adsorption rate was very fast (around 15min). Batch mode experiments and kinetic regression results showed that the adsorption process was more accurately represented by a pseudo second-order model. Freundlich isotherm model was superior to the Langmuir isotherm model. FT-IR studies revealed that adsorption process was due to adsorption mediated by different functional groups present on the coffee surface.