Boron isotope variations of Franciscan serpentinites, northern California

• Published in: Lithos 2019-06, Vol.334-335, p.180-189
• Main Authors: Yamada, Chinatsu, Tsujimori, Tatsuki, Chang, Qing, Kimura, Jun-Ichi
• Format: Article
• Language: English
• Subjects: Boron isotope; California Coast Ranges; Franciscan complex; Serpentinites
• ISSN: 0024-4937; 1872-6143
• DOI: 10.1016/j.lithos.2019.02.004

Serpentinites and serpentinized mantle peridotites with various tectonic origins occur in the Franciscan Complex of the Northern California Cordillera, USA. Boron isotopes of serpentinites differentiate with fluid-mediated processes, and have great potential for key geologic markers in convergent margins. To understand boron isotope behavior within the Franciscan subduction zone system, we apply a newly developed ablation volume correction (AVC) method for in-situ isotope/elemental analyses using a laser-ablation multiple collector inductively-coupled-plasma mass spectrometry (LA-MC-ICPMS) on seventeen different Franciscan serpentinites (sensu lato) collected from eight separate areas. Boron abundances and isotope compositions of the studied serpentinites show large variations B = 1.6–239 μg·g−1, δ11B = −12.0 to +24.4‰, which allow to discriminate the serpentinites into two groups: (1) a lighter δ11B of −12.0 to +8.8‰ with a lesser B  ~2 GPa. Preferential partitioning of 11B into fluids released from the subducted slab at shallow leaves lighter δ11B in the slab resulting in lighter δ11B in the deep slab fluids. In contrast, the blueschist-absent serpentinites with heavier δ11B may have formed at a shallow environment where shallow slab or hydrothermal fluids with heavier 11B were present. Lesser versus greater amounts of B in the deep versus shallow serpentinites are also consistent with the dehydration profile of B from a slab. Our results show the versatility of boron isotopes and composition for identification of the origin of serpentinite in Pacific-type orogenic belts. •B isotope compositions of Franciscan serpentinites (17 samples from 8 localities) were determined by LA-MC-ICPMS.•The B isotope composition discriminates the serpentinites into two groups.•Serpentinites associated with blueschists are characterized by low δ11B (−12 to +8.8‰).•Serpentinites without blueschists are characterized by high δ11B (+7.2 to +24.4‰).•The results show the versatility of B isotopes for identification of the origin of serpentinite.