Composite thin film of silica hollow spheres and waterborne polyurethane: Excellent thermal insulation and light transmission performances

• Published in: Materials chemistry and physics 2012-04, Vol.133 (2-3), p.642-648
• Main Authors: Liao, Yuchao, Wu, Xiaofeng, Wang, Zhen, Yue, Renliang, Liu, Gang, Chen, Yunfa
• Format: Article
• Language: English
• Subjects: A. Insulators; A. Optical materials; B. Finite element analysis; D. Thermal conductivity
• ISSN: 0254-0584; 1879-3312
• DOI: 10.1016/j.matchemphys.2012.01.041

[Display omitted] ► Silica hollow spheres are selected as the thermal insulation additives. ► KH550 and HCl together enhance the compatibility between the filler and substrate.► Finite element simulation is used to confirm the effectiveness of modification method. ► The composite behaves excellent insulation coupling with light transmission. Silica hollow spheres treated by 3-aminopropyltriethoxysilane (KH550) and hydrochloric acid showed good compatibility with polyurethane due to the improved functional group matching and charge matching between them. The resultant composite thin film exhibited excellent thermal insulation (0.05Wm−1K−1) and light transmission (above 80%), which were quantitatively evaluated by thermo-resistance superposition method and UV–vis spectra, respectively. Moreover, finite element simulation was used to calculate thermal conductivity of the composite thin film. The simulated value was close to the experimental one, which confirmed the effectiveness of the modifications.