Magnesium ferrite/titanium dioxide/reduced graphene oxide composite photocatalyst for degradation of crystal violet under ultraviolet irradiation

• Published in: Materials chemistry and physics 2023-06, Vol.301, p.127661, Article 127661
• Main Authors: Lin, Tong Hoang, An, Hoang, Nam, Nguyen Thanh Hoai, Hai, Nguyen Duy, Binh, Thoi Le Nhat, Cong, Che Quang, Trinh, Le Nguyen Thuc, Huy, Nguyen Le Hoang, Buu, Ton That, Cong Minh, Dang Thanh, Phong, Mai Thanh, Hieu, Nguyen Huu
• Format: Article
• Language: English
• Subjects: Graphene oxide; Magnesium ferrite; Photodegradation; Titanium dioxide
• ISSN: 0254-0584
• DOI: 10.1016/j.matchemphys.2023.127661

Critical water pollution due to human activities is currently a major issue that requires immediate and potent solutions. Therefore, the study focuses on the synthesis of the three-component nanocomposite magnesium ferrite/titanium dioxide/reduced graphene oxide aerogel (MFO/TiO2/rGOA – MTG) via the hydrothermal-assisted co-precipitation method. Characterization results of the synthesized materials revealed the successful incorporation of MFO and TiO2 nano/microparticles on the rGO substrate. In addition, the composite was utilized as a photocatalyst to decompose crystal violet (CV) under UV irradiation. Additionally, the effect of MFO content on the photodegradation efficiency was thoroughly investigated, which acquired excellent efficiency of over 99%. The reusability of MTG was also evaluated, retaining good performance after five reusing cycles. Besides, the photocatalytic activity was further examined through the first-ordered kinetics model based on the obtained experimental data. And free radicals, including •O2−, h+, and •OH, were elucidated to play exquisite roles in the CV removal process to subsequently propose an appropriate degradation mechanism using the MTG photocatalyst. From the aforementioned results, the innovative strategy in preparing the multi-component MTG composite potentially helps expand the applications in dye-polluted wastewater remediation. [Display omitted] •The MFO/TiO2/rGOA was synthesized via hydrothermal-assisted co-precipitation method.•The photodegradation efficiency of MTG-150 remains above 80% with CV from 10 to 50 mg/L.•MTG shows great reusability after 5 cycles, retaining 98% of the initial performance.•Free radicals play exquisite roles in the removal of CV, formed by MTG photocatalyst.