Investigation on the surface modification of TiO2 nanohexagon arrays based photoanode with SnO2 nanoparticles for highly-efficient dye-sensitized solar cells

• Published in: Materials research bulletin 2019-01, Vol.109, p.21-28
• Main Authors: Javed, Hafiz Muhammad Asif, Que, Wenxiu, Yin, Xingtian, Kong, Ling Bing, Iqbal, Javed, Salman Mustafa, M.
• Format: Article
• Language: English
• Subjects: Anodization; Dye-sensitized solar cells; SnO2/TiO2 heterojunction; TiO2 nanohexagon arrays
• ISSN: 0025-5408; 1873-4227
• DOI: 10.1016/j.materresbull.2018.09.016

[Display omitted] •SnO2 was introduced into the TiO2 nanohexagon arrays by using a one-step facile immersion approach.•The SnO2 nanoparticles had a superior light harvesting capability owe to the higher surface area for dye uploading and the high electron mobility.•The SnO2/TNHAs heterojunction based DSSC had a power conversion efficiency of 6.43%. An efficient-photoanode for the dye-sensitized solar cells (DSSCs) should have several features, such as high dye-uploading, favorable energy band-gaps and excellent capability in electronic-transport. Herein, TiO2 nanohexagon arrays (TNHAs) were fabricated by using an electrochemical anodization process. Then, TNHAs were attached onto the FTO glass for front-illuminated approach of the DSSCs. SnO2 is a promising wide band-gap material for DSSCs due to its high electron-mobility. To enhance the performance of DSSCs, SnO2 nanoparticles were offered into the TNHAs by using a one-step facile immersion approach in 0.25 M K2SnO3 solution for 30 min. The as-fabricated SnO2/TNHAs were utilized as the efficient-photoanodes for DSSCs. The SnO2 nanoparticles have a superior light harvesting capability owe to the higher upper-surface area for maximum dye-uploading and the high electron-mobility. The SnO2/TNHAs based DSSC had a PCE of 6.43%, which was 1.34 fold higher than those of pure TNHAs. Furthermore, IPCE and the amount of dye adsorption were also improved.