Hydrothermal synthesis, crystal structure and characterization of LiCoP5O14·H2O: A new condensed layered penta phosphate crystals

A new family of condensed hydrated lithium cobalt penta phosphate (LiCoP5O14·H2O) crystals were synthesized by hydrothermal technique and characterized by X-ray diffraction method. The compound crystallizes in monoclinic system with space group P21/c and cell parameters a=10.788(4) Å, b=9.761(3) Å,...

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Bibliographic Details
Published in:Materials letters 2006-05, Vol.60 (9-10), p.1122-1127
Main Authors: Gopalakrishna, G.S., Mahesh, M.J., Mahendra, M., Ashamanjari, K.G., Prasad, J. Shashidhara
Format: Article
Language:English
Subjects:
Crystal growth
Crystal structure
Inorganic compounds
X-ray diffraction
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Summary:A new family of condensed hydrated lithium cobalt penta phosphate (LiCoP5O14·H2O) crystals were synthesized by hydrothermal technique and characterized by X-ray diffraction method. The compound crystallizes in monoclinic system with space group P21/c and cell parameters a=10.788(4) Å, b=9.761(3) Å, c=9.788(5) Å, β=101.249(1) Å, Z=4, exhibiting layer type polymeric structure. DTA study indicates that this compound has low thermal stability and magnetically frequency dependent paramagnetic behaviour.
ISSN:0167-577X
1873-4979
DOI:10.1016/j.matlet.2005.04.065