Simple and scalable preparation of reduced graphene oxide–silver nanocomposites via rapid thermal treatment

• Published in: Materials letters 2012-12, Vol.89, p.180-183
• Main Authors: Zainy, M., Huang, N.M., Vijay Kumar, S., Lim, H.N., Chia, C.H., Harrison, I.
• Format: Article
• Language: English
• Subjects: acetates; Graphene; grinding; heat treatment; Nanocomposites; Nanoparticles; nanosilver; particle size; Raman spectroscopy; Rapid thermal treatment; scanning electron microscopes; silver; surfactants; transmission electron microscopy; ultraviolet-visible spectroscopy; X-ray diffraction
• ISSN: 0167-577X; 1873-4979
• DOI: 10.1016/j.matlet.2012.08.101

In this study, we describe a simple, straightforward and scalable method for the preparation of high purity reduced graphene oxide/silver (rGO/Ag) nanocomposites via a rapid thermal reduction method. Silver acetate (AgCH3O2) was used as a silver precursor and graphene oxide (GO) served as a substrate for the Ag nanoparticles. The nanocomposites were prepared by grinding GO and the silver precursor, and were rapidly treated at 1000°C in a furnace for 20s under an ambient atmosphere. The obtained rGO/Ag nanocomposites were confirmed by ultraviolet–visible spectroscopy (UV–vis), X-ray diffraction (XRD), and Raman spectroscopy. field emission scanning electron microscope (FESEM) and transmission electron microscope (TEM) images showed uniformly distributed Ag nanoparticles on the reduced GO surface. The average particle size of the formed Ag nanoparticles was 16.9±3.5nm. Since the preparation method does not involve any addition of a surfactant or stabilizer, the obtained nanocomposites are of high purity. ► High purity rGO/Ag nanocomposites were prepared by rapid thermal reduction method. ► Ag nanoparticles (∼17nm) were uniformly distributed on the rGO surface. ► rGO/Ag nanocomposites show surface-enhanced Raman scattering (SERS) effects.