Visible light driven photocatalyst NiFe2O4/Ag2WO4 nanocomposite for the degradation of tetracycline (TC-HCl) antibiotics

[Display omitted] •NiFe2O4/Ag2WO4 improved TC-HClphotocatalytic degradation under visible light.•NiFe2O4/Ag2WO4 demonstrated enhanced photodegradation upto 92.3% against tetracycline.•NiFe2O4/Ag2WO4 showed excellent rate constant values (k) of 0.0315 min−1. The use of tetracycline (TC-HCl) antibioti...

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Published in:Materials letters 2024-12, Vol.377, p.137391, Article 137391
Main Authors: Asif, Muhammad, Latif, Misbah, Yang, Jin, Wahab, Rizwan, Rasool, Binesh, Hammad Aziz, Muhammad
Format: Article
Language:English
Subjects:
Electron spin resonance (ESR)
FTIR
Liquid chromatography-mass spectrometry (LC-MS)
Nanocomposites
Tetracycline (TC-HCl)
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container_start_page 137391
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creator Asif, Muhammad
Latif, Misbah
Yang, Jin
Wahab, Rizwan
Rasool, Binesh
Hammad Aziz, Muhammad
description [Display omitted] •NiFe2O4/Ag2WO4 improved TC-HClphotocatalytic degradation under visible light.•NiFe2O4/Ag2WO4 demonstrated enhanced photodegradation upto 92.3% against tetracycline.•NiFe2O4/Ag2WO4 showed excellent rate constant values (k) of 0.0315 min−1. The use of tetracycline (TC-HCl) antibiotics is harmful to ecosystems worldwide. Herein, NiFe2O4/Ag2WO4nanocomposite (NC) was synthesized via the hydrothermal method for the degradation of tetracycline. The photodegradation efficiency of TC-HCl reached 92.3% after being exposed to visible light for 90 min. Additionally, the stability of the NiFe2O4/Ag2WO4nanocomposite is maintained during the photodegradation of tetracycline, as verified by the recyclability test. Degradation efficiency up to 83% was still present after six cycles. The presence of DMPO-∙O2- and DMPO-•OH is confirmed by the ESR study, when the visible exposure period expanded to 15 min. High photocatalytic performance, strong recyclability, and stability make NiFe2O4/Ag2WO4a potential antibiotic photodegradation candidate.
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subjects Electron spin resonance (ESR)
FTIR
Liquid chromatography-mass spectrometry (LC-MS)
Nanocomposites
Tetracycline (TC-HCl)
title Visible light driven photocatalyst NiFe2O4/Ag2WO4 nanocomposite for the degradation of tetracycline (TC-HCl) antibiotics
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