Carbon nitride photocatalyst with internal electric field induced photogenerated carriers spatial enrichment for enhanced photocatalytic water splitting

• Published in: Materials today (Kidlington, England) England), 2022-09, Vol.58, p.100-109
• Main Authors: Zhou, Qixin, Guo, Yang, Ye, Zhiqiang, Fu, Yunzhi, Guo, Yan, Zhu, Yongfa
• Format: Article
• Language: English
• Subjects: Graphitic carbon nitride; Internal electric field; Overall water splitting; Photocatalysis
• ISSN: 1369-7021; 1873-4103
• DOI: 10.1016/j.mattod.2022.06.009

A carbon nitride nanosheet homojunction with spatial separation of electrons-enriched and holes-enriched regions, is successfully constructed to realize the directional charge-carrier transfer, the avoidance of water splitting reverse reaction, and efficient photocatalytic water splitting activity. The notable H2 evolution rate of (1270.5 μmol h−1, with scavenger) and overall water splitting solar-to-hydrogen efficiency of 0.14% is achieved. [Display omitted] Photocatalytic water splitting is a cost-effective way to convert sustainable solar energy into chemical energy. Among various photocatalytic systems, coupling the H2- and O2- evolving photocatalysts has been widely used in photocatalytic water splitting. However, due to the close spatial distance between surface electrons and surface holes, this heterogeneous material easily catalyzes the unwanted reverse reaction, limiting the solar energy conversion efficiency. Here we present a carbon nitride nanosheet (CNN) homojunction which possesses electrons-enriched region and holes-enriched region induced by the interfacial internal electric field. The reverse reactions are significantly suppressed by benefiting from the spatial separation of the oxidation (+2.21 V) and reduction (-1.19 V) regions. The homojunction exhibits efficient photocatalytic activity for H2 and O2 evolution (1270.5 and 36.0 μmol h−1) with the scavenger. Meanwhile, the solar-to-hydrogen efficiency of overall water splitting was improved to 0.14%. This research provides a new way for semiconductor design in solar energy conversion applications.