A hybrid processing method for high performance hydrogen-selective silica membranes

• Published in: Journal of membrane science 2007-07, Vol.297 (1), p.5-9
• Main Authors: Gopalakrishnan, Suraj, Yoshino, Yasushi, Nomura, Mikihiro, Nair, Balagopal N., Nakao, Shin-Ichi
• Format: Article
• Language: English
• Subjects: CVD; Hydrogen separation; Membrane reactor; Silica membranes; Sol–gel
• ISSN: 0376-7388; 1873-3123
• DOI: 10.1016/j.memsci.2007.03.034

Development of high performance hydrogen-selective inorganic membrane has become an important requisite for the production of hydrogen, an energy carrier that could cater the ongoing energy revolution. This paper describes a novel, hybrid method to process high performance hydrogen perm-selective membranes by the rapid CVD modification of a sol–gel silica layer. The initial N 2 permeance values through a membrane were brought down by four orders of magnitude to 2.74 × 10 −10 mol m −2 s −1 Pa −1 within 5 min of CVD, while maintaining the H 2 permeance values as high as 6.43 × 10 −7 mol m −2 s −1 Pa −1 (H 2/N 2 = 2300). It is likely that the reduction in the CVD zone thickness achieved by the presence of pre-existing sol–gel silica layer is the reason for the rapid modification of the pore structure to high performance membranes.