Hydrogen permeability and chemical stability of Ni–BaZr0.1Ce0.7Y0.1Yb0.1O3−δ membrane in concentrated H2O and CO2

• Published in: Journal of membrane science 2014-10, Vol.467, p.85-92
• Main Authors: Fang, Shumin, Brinkman, Kyle S., Chen, Fanglin
• Format: Article
• Language: English
• Subjects: Barium cerate; Chemical stability; Chemistry; Colloidal state and disperse state; Exact sciences and technology; General and physical chemistry; High temperature proton conductor; Hydrogen permeation; Membranes; Reverse water gas shift reaction
• ISSN: 0376-7388; 1873-3123
• DOI: 10.1016/j.memsci.2014.05.008

Ni–BaZr0.1Ce0.7Y0.1Yb0.1O3−δ (Ni–BZCYYb) membrane shows improved and stable performance in dry H2 and CO2 (Fang et al., ACS Appl. Mater. Interfaces 6 (2014) 725–730). However, the stream from steam methane reforming contains high contents of H2O, CO2, and CO, which poses crueler challenges to the chemical stability of Ni–BZCYYb membrane than dry H2 and CO2. In this work, we tested the Ni–BZCYYb membrane in wet H2 and CO2 which generated high content of H2O and CO due to reverse water gas shift (RWGS) reaction at high temperature. High content of H2O improves the proton conductivity of BZCYYb and hydrogen transport through the membrane. On the other hand, H2 content reduction and decomposition of BZCYYb promoted by high content of H2O lead to performance degradation. The steady-state hydrogen flux may increase or decrease depending on the balance among these effects. Besides, CO-induced Ni corrosion was found in both surface and bulk due to metal dusting. In general, Ni–BZCYYb membrane still displayed much better performance stability in wet H2 and CO2 than Ni–BaCe0.8Y0.2O3−δ and Ni–BaZr0.1Ce0.7Y0.2O3−δ composites, making it a candidate material system for further studies aimed at membrane processing of hydrocarbons. [Display omitted] •Ni–BZCYYb presents better performance stability than Ni–BZCY and Ni–BCY membranes.•RWGS reaction leads to drastic increase in H2O and CO content.•High content of H2O improves hydrogen flux.•High content of H2O accelerates the decomposition of BZCYYb phase in CO2.•CO causes Ni corrosion in the surface and bulk through metal dusting.