Novel quaternized polyvinyl alcohol/quaternized chitosan nano-composite as an effective hydroxide-conducting electrolyte

• Published in: Journal of membrane science 2015-07, Vol.485, p.17-29
• Main Authors: Liao, Guan-Ming, Yang, Chun-Chen, Hu, Chien-Chieh, Pai, Yu-Li, Lue, Shingjiang Jessie
• Format: Article
• Language: English
• Subjects: Conductivity enhancement; Direct alcohol alkaline fuel cells; Methanol permeability; Nano-composite electrolyte; Quaternized anion-exchange membrane
• ISSN: 0376-7388; 1873-3123
• DOI: 10.1016/j.memsci.2015.02.043

A novel polymer composite electrolyte consisting of quaternized polyvinyl alcohol (Q-PVA) and quaternized chitosan nano-particles (Q-chitosan) is synthesized for use in a direct alcohol alkaline fuel cell (DAAFC). The quaternization efficiencies of PVA and chitosan particles are 2.6% and 39%, respectively. Incorporation of 5% Q-chitosan nano-particles into the Q-PVA matrix results not only in an increased ion-exchange capacity but also a decreased polymer crystallinity and higher free volume hole density, which significantly enhance ion conduction. The shrunk polymer free volume size suppresses methanol permeability in the Q-PVA/Q-chitosan composite. In addition, the resulting nano-composite exhibited an inhibited in-plane swelling ratio without sacrificing the alkali uptake level. The KOH-doped Q-PVA/Q-chitosan was resistant to the Fenton reagent. In DAAFCs, a maximum power density of 73mWcm–2 is achieved using the Q-PVA/5%Q-chitosan electrolyte when fed with 2M methanol at 60°C or 59mWcm–2 with 3M ethanol at 60°C. The resulting maximum power densities are higher than most literature data. The alkaline fuel cell demonstrated stable long-term power output for at least 230h. This result confirms that the Q-PVA/Q-chitosan electrolyte exhibits great potential for future commercialization. [Display omitted] •A novel electrolyte consisting of Q-PVA and Q-chitosan was achieved for fuel cells.•Shrunk polymer free volume size suppressed methanol permeability in the composite.•Q-chitosan enhanced ionic conducting via hopping mechanism.•Q-chitosan nano-particles increased polymer free volume, promoting ion diffusion.•The resulting Pmax was higher than most literature data reported for DAAFCs.