Photodimerization of the anthracene ruthenium complexes [(C 5Me 4R)Ru(η 6-C 14H 10)] + (R=Me, CH 2OMe)

The dimerization of the anthracene ruthenium complexes [(C 5Me 4R)Ru(η 6-C 14H 10)] + (R=Me, CH 2OMe) under visible-light irradiation gives dications [(μ-η 6:η 6-C 28H 20)Ru 2(C 5Me 4R) 2] 2+ with the most distant position of the Ru(C 5Me 4R) fragments; the structure of [(μ-η 6:η 6-C 28H 20)Ru 2(C 5...

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Bibliographic Details
Published in:Mendeleev communications 2011-11, Vol.21 (6), p.309-311
Main Authors: Karslyan, Eduard E., Konovalov, Andrew I., Borissova, Alexandra O., Petrovskii, Pavel V., Kudinov, Alexander R.
Format: Article
Language:English
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Summary:The dimerization of the anthracene ruthenium complexes [(C 5Me 4R)Ru(η 6-C 14H 10)] + (R=Me, CH 2OMe) under visible-light irradiation gives dications [(μ-η 6:η 6-C 28H 20)Ru 2(C 5Me 4R) 2] 2+ with the most distant position of the Ru(C 5Me 4R) fragments; the structure of [(μ-η 6:η 6-C 28H 20)Ru 2(C 5Me 4CH 2OMe) 2](PF 6) 2 was established by X-ray diffraction.
ISSN:0959-9436
DOI:10.1016/j.mencom.2011.11.005