Crystal structure and magnetic properties of a tetranuclear carbonate-bridged CuII complex with a Schiff base compartmental ligand with the N2OS2 donor set

A carbonate-bridged tetranuclear CuII complex of the general formula [(Cu2L)2CO3]·2MeCN (L is triply deprotonated Schiff base condensation product of 1,3-diaminopropan-2-ol and 1-phenyl-3-methyl-4-formyl-5-mercaptopyrazole) has been obtained by the slow crystallization of dinuclear complex [(Cu2L)CC...

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Bibliographic Details
Published in:Mendeleev communications 2015-01, Vol.25 (1), p.62-64
Main Authors: Uraev, Ali I., Popov, Leonid D., Levchenkov, Sergey I., Shcherbakov, Igor N., Suponitsky, Kyrill Yu, Garnovskii, Dmitry A., Lukov, Vladimir V., Kogan, Victor A.
Format: Article
Language:English
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Summary:A carbonate-bridged tetranuclear CuII complex of the general formula [(Cu2L)2CO3]·2MeCN (L is triply deprotonated Schiff base condensation product of 1,3-diaminopropan-2-ol and 1-phenyl-3-methyl-4-formyl-5-mercaptopyrazole) has been obtained by the slow crystallization of dinuclear complex [(Cu2L)CCl3COO] from acetonitrile and studied by X-ray diffraction and low-temperature magnetic measurements.
ISSN:0959-9436
DOI:10.1016/j.mencom.2015.01.023