Synthesis and properties of a novel porphyrin–fullerene triad assembled through donor–acceptor bonding

[Display omitted] Complexation of (hydroxy)(oxo)(5,10,15,20-tetraphenylporphyrinato) molybdenum(v) with 2’,5’-di(2-pyridyl)-1’-(3-pyridylmethyl) pyrrolidino[70]fullerene leading to a new donor–acceptor triad is characterized by quantitative description of the equilibrium and the reaction rate. The p...

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Published in:Mendeleev communications 2018-07, Vol.28 (4), p.426-428
Main Authors: Motorina, Elena V., Lomova, Tatyana N., Klyuev, Mikhail V.
Format: Article
Language:English
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Summary:[Display omitted] Complexation of (hydroxy)(oxo)(5,10,15,20-tetraphenylporphyrinato) molybdenum(v) with 2’,5’-di(2-pyridyl)-1’-(3-pyridylmethyl) pyrrolidino[70]fullerene leading to a new donor–acceptor triad is characterized by quantitative description of the equilibrium and the reaction rate. The prospects of the triad as a photosynthetic antenna imitator and an active layer in solar energy conversion devices are substantiated.
ISSN:0959-9436
DOI:10.1016/j.mencom.2018.07.029