Simple H2-free hydrogenation of unsaturated monoterpenoids catalyzed by Raney nickel

[Display omitted] A series of monoterpenoids (citral, carvone, menthone, camphor) as well as cyclohexanone and hex-5-en-2-one were subjected to transfer hydrogenation with PriOH/Raney nickel system at 82 or 150°C. Among monoterpenoids, citral and carvone underwent full conversion at 82°C within 5h....

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Bibliographic Details
Published in:Mendeleev communications 2019-07, Vol.29 (4), p.380-381
Main Authors: Philippov, Alexey A., Chibiryaev, Andrey M., Martyanov, Oleg N.
Format: Article
Language:English
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Summary:[Display omitted] A series of monoterpenoids (citral, carvone, menthone, camphor) as well as cyclohexanone and hex-5-en-2-one were subjected to transfer hydrogenation with PriOH/Raney nickel system at 82 or 150°C. Among monoterpenoids, citral and carvone underwent full conversion at 82°C within 5h.
ISSN:0959-9436
DOI:10.1016/j.mencom.2019.07.006