Synthesis, crystal structures and solid state reactions of zinc(ii) cyclobutane-1,1′-dicarboxylates containing 1,2-bis(pyrid-4 yl)ethylene

[Display omitted] Synthesis and response towards heating and UV irradiation of two novel zinc(II) cyclobutane-1,1′-dicarboxylate complexes were examined using X-ray diffraction, FT-IR and 1H NMR spectroscopy. One of the complexes underwent a photoinitiated solid state transformation of 1,2-bis(pyrid...

Full description

Saved in:
Bibliographic Details
Published in:Mendeleev communications 2019-11, Vol.29 (6), p.643-645
Main Authors: Ushakov, Ivan E., Goloveshkin, Alexander S., Zorina-Tikhonova, Ekaterina N., Chistyakov, Aleksandr S., Sidorov, Aleksei A., Eremenko, Igor L., Volodin, Alexander D., Vologzhanina, Anna V.
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:[Display omitted] Synthesis and response towards heating and UV irradiation of two novel zinc(II) cyclobutane-1,1′-dicarboxylate complexes were examined using X-ray diffraction, FT-IR and 1H NMR spectroscopy. One of the complexes underwent a photoinitiated solid state transformation of 1,2-bis(pyrid-4-yl)ethylene into 1,2,3,4-tetrakis(pyrid-4-yl)cyclobutane. A preliminary dehydration of this solid decreases the conversion rate of photoreaction.
ISSN:0959-9436
DOI:10.1016/j.mencom.2019.11.012