Regioselective synthesis of 1-azinyl-1′-isopropenylferrocenes

[Display omitted] The Friedel–Crafts acetylation (Ac2O/AlCl3) reaction of azinylferrocenes occurs regioselectively at position 1′. Acetylated derivatives upon reaction with Ph3P=CH2 give the corresponding 1-azinyl-1′-isopropenylferrocenes.

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Bibliographic Details
Published in:Mendeleev communications 2020-03, Vol.30 (2), p.209-210
Main Authors: Musikhina, Alexandra A., Utepova, Irina A., Chupakhin, Oleg N., Suvorova, Anna I., Zyryanova, Elena Yu
Format: Article
Language:English
Subjects:
azines
ferrocenes
Friedel–Crafts acylation
isopropenylferrocene
regioselective synthesis
Wittig reaction
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Summary:[Display omitted] The Friedel–Crafts acetylation (Ac2O/AlCl3) reaction of azinylferrocenes occurs regioselectively at position 1′. Acetylated derivatives upon reaction with Ph3P=CH2 give the corresponding 1-azinyl-1′-isopropenylferrocenes.
ISSN:0959-9436
DOI:10.1016/j.mencom.2020.03.026