TEMPO-mediated radical polymerization in the synthesis of poly(methyl methacrylate) macromonomer

[Display omitted] A new synthesis of poly(methyl methacrylate) vinylterminated macromonomer is performed using the disproportionation between propagating methyl methacrylate radical and nitroxide TEMPO. The ability of the macromonomer to polymerize and copolymerize with styrene and poly(ethylene gly...

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Bibliographic Details
Published in:Mendeleev communications 2020-09, Vol.30 (5), p.627-629
Main Authors: Zaremski, Mikhail Yu, Aliev, Elvin E., Garina, Elizaveta S., Melik-Nubarov, Nikolay S.
Format: Article
Language:English
Subjects:
brush-like copolymers
disproportionation
macromonomers
nitroxides
poly(methyl methacrylate)
radical polymerization
terminal vinyl group
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Summary:[Display omitted] A new synthesis of poly(methyl methacrylate) vinylterminated macromonomer is performed using the disproportionation between propagating methyl methacrylate radical and nitroxide TEMPO. The ability of the macromonomer to polymerize and copolymerize with styrene and poly(ethylene glycol) methacrylate was confirmed by GPC and isothermal calorimetry.
ISSN:0959-9436
DOI:10.1016/j.mencom.2020.09.025