Synthesis of conjugates of 5,15-disubstituted aminoporphyrins and terpyridine derivatives with potential chelating properties

[Display omitted] meso-Arylporphyrin containing two external chelating 2,2':6',2'-terpyridine fragments and its zinc complex were synthesized. The key step comprised the amide bond formation between the porphyrin diamine derivative and 4'-(4-carboxyphenyl)-2,2':6',2...

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Bibliographic Details
Published in:Mendeleev communications 2022-09, Vol.32 (5), p.675-677
Main Authors: Vyalba, Fedor Yu, Ivantsova, Anastasia V., Zhdanova, Kseniya A., Usachev, Maxim N., Gradova, Margarita A., Bragina, Natal'ya A.
Format: Article
Language:English
Subjects:
chelating groups
photodiagnostics
photodynamic therapy
porphyrins
terpyridine
Zn complexes of porphyrins
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Summary:[Display omitted] meso-Arylporphyrin containing two external chelating 2,2':6',2'-terpyridine fragments and its zinc complex were synthesized. The key step comprised the amide bond formation between the porphyrin diamine derivative and 4'-(4-carboxyphenyl)-2,2':6',2'-terpyridine. The compounds obtained seem to be potent for photodynamic therapy and diagnosis.
ISSN:0959-9436
DOI:10.1016/j.mencom.2022.09.036