Crystal growth and thermodynamic properties of lithium tungstate doped by 4% molybdenum

[Display omitted] For the first time, single crystal of Li2W0.96Mo0.04O4 has been grown by low-temperature-gradient Czochralski technique. The thermodynamic characteristics (standard formation enthalpy and lattice enthalpy) that are necessary to improve the growth technology have been studied by sol...

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Bibliographic Details
Published in:Mendeleev communications 2022-11, Vol.32 (6), p.834-836
Main Authors: Matskevich, Nata I., Shlegel, Vladimir N., Semerikova, Anna N., Grigorieva, Veronika D., Korolkov, Ilya V., Tkachev, Eugeniy N.
Format: Article
Language:English
Subjects:
crystal growth
formation enthalpy
lattice enthalpy
lithium tungstate
molybdenum
thermodynamics–structure correlation
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Summary:[Display omitted] For the first time, single crystal of Li2W0.96Mo0.04O4 has been grown by low-temperature-gradient Czochralski technique. The thermodynamic characteristics (standard formation enthalpy and lattice enthalpy) that are necessary to improve the growth technology have been studied by solution calorimetry. For Li2W1–xMoxO4 single crystals, correlations of lattice enthalpies and standard formation enthalpies with tolerance factor were found.
ISSN:0959-9436
DOI:10.1016/j.mencom.2022.11.042