Graphene oxide/doped polyindole/hydroxypropyl cellulose coated on interdigitated electrode as methanol sensor

• Published in: Microchemical journal 2021-12, Vol.171, p.106889, Article 106889
• Main Authors: Phasuksom, Katesara, Ouajai, Walaiporn Prissanaroon, Sirivat, Anuvat
• Format: Article
• Language: English
• Subjects: Chemical sensor; Conductive polymer; Graphene oxide; Hydroxypropyl cellulose; Interdigitated electrode; Polymer composite
• ISSN: 0026-265X; 1095-9149
• DOI: 10.1016/j.microc.2021.106889

[Display omitted] •The GO/dPIn mixed hydroxypropyl cellulose (HPC) is coated on interdigitated electrode.•Hydroxypropyl cellulose enhances both adhesion efficiency and methanol response.•The sensor is integrated with a portable sensor platform via NFC.•The portable sensor shows sensitivity of 0.0123 ppm−1 with response time 12–50 s. GO/dPIn are coated on an interdigitated electrode for the methanol vapor detection. Initially, the composite sensors are laboratory tested for the material selection. Various effects are investigated namely: solvent types for preparing the composites; mixing with hydroxypropyl cellulose (HPC) to improve the methanol response and surface adhesion; number of coating layers; and also sensor performances. The GO/dPIn prepared in acetone provides the highest relative current response towards methanol. The GO/dPIn/HPC achieves not only a good adhesion but also an increase in methanol response, especially 0.5 g of GO/dPIn mixed with 0.75 g of HPC. One coating layer, the relative current response reaches the highest value under N2. However, it decreases in ambient air due to the effects of humidity and interfering gases. Besides, the high applied voltage leads to the increase in methanol response but the sensing layer is damaged by heat generation. Finally, the sensor is integrated with a portable sensor platform, connected by NFC to a mobile phone. The sensitivity is 0.0123 ppm−1 in the dynamic range 97–1041 ppm at the applied voltage of 0.8 V under ambient air, whereas the response and recovery times are within 12–50 s depending on methanol concentration.