Insights on Adsorption Characterization of Metal-Organic Frameworks: A Benchmark Study on the Novel soc-MOF

In order to explore the potential of novel open metal organic frameworks (MOFs) with soc topology for gas storage applications, we performed a systematic physical adsorption study with Hydrogen, Methane and Carbon dioxide as adsorptives over a wide range of temperatures (77–323 K) and pressures (0–5...

Full description

Saved in:
Bibliographic Details
Published in:Microporous and mesoporous materials 2010-04, Vol.129 (3), p.345-353
Main Authors: Moellmer, J., Celer, E.B., Luebke, R., Cairns, A.J., Staudt, R., Eddaoudi, M., Thommes, M.
Format: Article
Language:English
Subjects:
Adsorption
Characterization
Chemistry
Colloidal state and disperse state
Exact sciences and technology
Gas separation
General and physical chemistry
High pressure
MOF
Porous materials
Surface physical chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:In order to explore the potential of novel open metal organic frameworks (MOFs) with soc topology for gas storage applications, we performed a systematic physical adsorption study with Hydrogen, Methane and Carbon dioxide as adsorptives over a wide range of temperatures (77–323 K) and pressures (0–5 MPa) by using a volumetric low pressure adsorption analyzer equipped with a cryostat, and a high pressure gravimetric system. The advanced interpretation of our systematic adsorption data in combination with the results from a comprehensive structural and surface characterization allows one assessing the potential of these novel MOFs for gas storage and separation applications.
ISSN:1387-1811
1873-3093
DOI:10.1016/j.micromeso.2009.06.014