Self-assembled hierarchical porous layered double hydroxides by solvothermal method and their application for capacitors

• Published in: Microporous and mesoporous materials 2012-01, Vol.148 (1), p.159-165
• Main Authors: Song, Yanchao, Wang, Jun, Li, Zhanshuang, Guan, Dahui, Mann, Tom, Liu, Qi, Zhang, Milin, Liu, Lianhe
• Format: Article
• Language: English
• Subjects: Capacitors; Chemistry; Colloidal state and disperse state; Electrochemistry; Exact sciences and technology; General and physical chemistry; Hierarchical porous; Layered double hydroxides; Porous materials; Self-assembly; Solvothermal
• ISSN: 1387-1811; 1873-3093
• DOI: 10.1016/j.micromeso.2011.08.013

Self-assemble of Ni/Al layered double hydroxides (LDHs) with high specific surface area and high porosity via a facile and environmentally friendly solvothermal approach. [Display omitted] ► Self-assembled hierarchical porous layered double hydroxides by a facile and environmentally friendly solvothermal approach. ► High surface area and high porosity make LDHs display better electrochemical performance. ► A possible growth mechanism to explain the hierarchical structure is proposed. In this paper, for the first time, Ni/Al layered double hydroxides (LDHs) with high specific surface area and high porosity were developed via a facile and environmentally friendly solvothermal approach. The obtained Ni/Al LDHs have a diameter of 1–10 μm, which are self-assembled by 15 nm-sized primary particles and 200 nm size secondary particles. The BET surface area of the sample is determined to about 300 m 2 g −1, which is about three times than that prepared by conventional hydrothermal route. The average pore size is 3.97 nm. Notedly, the specific capacitance of this hierarchical porous Ni/Al LDHs reaches 477 F g −1 at a current density of 2.5 A g −1, which is nearly double that of Ni/Al LDHs synthesized by conventional hydrothermal procedure. The capacitance loss is less than 5% after 400 charge–discharge cycles, suggesting the high potential as electrode materials in electrochemical capacitors. The formation mechanism of self-assembled hierarchical porous Ni/Al LDHs through solvothermal method was also proposed.