Issues concerning soils treated with wastewater: Pedotechnical management with zeolitized tuffs as an option for turning N and P pollutants into potential fertilizers

• Published in: Microporous and mesoporous materials 2013-02, Vol.167, p.22-29
• Main Authors: Capra, Gian Franco, Duras, Maria Giustina, Vacca, Sergio, Grilli, Eleonora, Buondonno, Andrea
• Format: Article
• Language: English
• Subjects: Chemistry; Colloidal state and disperse state; Exact sciences and technology; General and physical chemistry; Ion-exchange; Municipal wastewater; Natural zeolites; Pedotechnique; Plant nutrients; Porous materials; Soil resilience; Surface physical chemistry; Zeolites: preparations and properties
• ISSN: 1387-1811; 1873-3093
• DOI: 10.1016/j.micromeso.2012.05.043

According to the increasing amount of zeolitized tuff in the investigated samples, WW was effectively cleaned, and N and P were retained as fertilizer pool for plant nutrition. [Display omitted] ► Two soils were amended with zeolitized tuffs (ZTs) and treated with wastewater. ► We studied the effects of amendment with ZTs in recovering N and P as nutrients. ► N and P decreased in the supernatant as ZT content in soil/zeolite samples increased. ► N and P in the soil/zeolite samples increased as ZT content increased. ► ZTs is an useful pedotechnical material to restore weakly resilient soils. We studied the effects of amendment with zeolitized tuffs (ZT) in recovering nitrogen and phosphorus as potential plant nutrients in soils treated with wastewater (WW). The surface horizon of two contrasting soils (a sandy, alkaline Entisol, and a sandy-loam, sub-acidic Alfisol), was pedotechnically managed with different ratios of Neapolitan Yellow Tuff (NYT) and a clinoptilolite bearing tuff (ZCL). It was then exposed to repeated treatments with ‘dirty’ municipal wastewater (DMW). Results showed that the presence of ZTs had several favorable effects. As concerns the aspect connected with the investigation into the supernatant/soil solution, total N and total P decreased sharply in the supernatant as ZT content in soil/zeolite samples increased. Large quantities of nitrate were removed from the solution, most probably via bio-chemical reaction. Investigation of the soil/zeolite samples after twelve consecutive treatment cycles showed that the concentration of the essential plant macronutrients N and P increased as ZT content increased. Overall, the ZTs added directly to the poorly-resilient soils appeared to be a useful amendment in reducing the pollutants load caused by irrigation with untreated wastewater. It also played a positive role in pedotechnique strategies, improving both the natural intrinsic soil resilience and soil functionality.