New biocides based on imidazolinium-functionalised hybrid mesoporous silica nanoparticles

Here, we report the development of a new biocide based on hybrid mesoporous silica nanoparticles (MSN). The MSN was synthesized by condensation method in emulsion followed by grafting with two different silylated ionic liquid moieties, namely butyl imidazolinium bromide and imidazolinium propansulfo...

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Bibliographic Details
Published in:Microporous and mesoporous materials 2022-09, Vol.343, p.112142, Article 112142
Main Authors: Vitale, Filippo, Saladino, Maria Luisa, Armetta, Francesco, Presentato, Alessandro, Alduina, Rosa, Mercadante, Alessandro, La Parola, Valeria, Giacalone, Francesco
Format: Article
Language:English
Subjects:
Biocides
Biodeterioration
Ionic liquids
Mesoporous silica nanoparticles
Preventive conservation
Stone conservation
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Summary:Here, we report the development of a new biocide based on hybrid mesoporous silica nanoparticles (MSN). The MSN was synthesized by condensation method in emulsion followed by grafting with two different silylated ionic liquid moieties, namely butyl imidazolinium bromide and imidazolinium propansulfonate betaine. Features of nanoparticles were characterized by Thermogravimetry, Infrared and ss-NMR Spectroscopy, and Transmission Electron Microscopy. The antibacterial properties were tested against a Gram-positive bacterial strain previously isolated from artefacts of interest in the field of Cultural Heritage. Interestingly, the hybrid material presents an antibacterial activity higher than its single constituents, showing a synergic effect probably due to the high local concentration of the ionic liquid anchored to nanoparticles. The more promising material was applied to fragments of stones retrieved from the Santa Margherita cave (Italy) and affected by bio-deterioration, comparing its antibacterial action with a commercial biocide. [Display omitted] •New biocides demonstrating the role of the imidazolinium salt as functionalisating agent in mesoporous silica.•Two different silylated ionic liquid moieties, namely a butyl imidazolinium bromide and an imidazolinium propansulfonate betaine, are grafted on silica mesoporous nanoparticles.•The hybrid has higher antibacterial activity than the single counterparts, showing a synergic effect due to the high concentration of the ionic liquid anchored.
ISSN:1387-1811
1873-3093
DOI:10.1016/j.micromeso.2022.112142